Activation and Reactivity of (NHC)Pd(allyl)Cl (NHC = N-Heterocyclic Carbene) Complexes in Cross-Coupling Reactions

Activation and Reactivity of (NHC)Pd(allyl)Cl (NHC = N-Heterocyclic Carbene) Complexes in Cross-Coupling Reactions

Mononuclear palladium-allyl complexes bearing one N-heterocyclic carbene (NHC) ligand have been synthesized. These complexes offer a straightforward entryway into a number of catalytic cycles by simple action of a base.

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Veröffentlicht in:Organometallics 2002-12, Vol.21 (25), p.5470-5472
Hauptverfasser: Viciu, Mihai S, Germaneau, Romain F, Navarro-Fernandez, Oscar, Stevens, Edwin D, Nolan, Steven P
Format: Artikel
Sprache:eng
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Zusammenfassung:Mononuclear palladium-allyl complexes bearing one N-heterocyclic carbene (NHC) ligand have been synthesized. These complexes offer a straightforward entryway into a number of catalytic cycles by simple action of a base.
ISSN:0276-7333
1520-6041
DOI:10.1021/om020804i