The First General Method for the Synthesis of Transition-Metal π Complexes of an Electronically Diverse Family of 1,2-Azaborolyls

A general method for the synthesis of new families of transition-metal-free 1,2-azaborolides (3) has been developed, based on a readily available precursor (1). These azaborolides react with a variety of transition-metal electrophiles to produce an unprecedented array of η5-azaborolyl adducts (4) (s...

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Veröffentlicht in:Organometallics 2002-10, Vol.21 (21), p.4323-4325
Hauptverfasser: Liu, Shih-Yuan, Hills, Ivory D, Fu, Gregory C
Format: Artikel
Sprache:eng
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