The First General Method for the Synthesis of Transition-Metal π Complexes of an Electronically Diverse Family of 1,2-Azaborolyls
A general method for the synthesis of new families of transition-metal-free 1,2-azaborolides (3) has been developed, based on a readily available precursor (1). These azaborolides react with a variety of transition-metal electrophiles to produce an unprecedented array of η5-azaborolyl adducts (4) (s...
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Veröffentlicht in: | Organometallics 2002-10, Vol.21 (21), p.4323-4325 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | A general method for the synthesis of new families of transition-metal-free 1,2-azaborolides (3) has been developed, based on a readily available precursor (1). These azaborolides react with a variety of transition-metal electrophiles to produce an unprecedented array of η5-azaborolyl adducts (4) (substituents bound to boron: nitrogen, oxygen, hydrogen, carbon, and phosphorus). |
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ISSN: | 0276-7333 1520-6041 |
DOI: | 10.1021/om020533b |