The First General Method for the Synthesis of Transition-Metal π Complexes of an Electronically Diverse Family of 1,2-Azaborolyls
A general method for the synthesis of new families of transition-metal-free 1,2-azaborolides (3) has been developed, based on a readily available precursor (1). These azaborolides react with a variety of transition-metal electrophiles to produce an unprecedented array of η5-azaborolyl adducts (4) (s...
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Veröffentlicht in: | Organometallics 2002-10, Vol.21 (21), p.4323-4325 |
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creator | Liu, Shih-Yuan Hills, Ivory D Fu, Gregory C |
description | A general method for the synthesis of new families of transition-metal-free 1,2-azaborolides (3) has been developed, based on a readily available precursor (1). These azaborolides react with a variety of transition-metal electrophiles to produce an unprecedented array of η5-azaborolyl adducts (4) (substituents bound to boron: nitrogen, oxygen, hydrogen, carbon, and phosphorus). |
doi_str_mv | 10.1021/om020533b |
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These azaborolides react with a variety of transition-metal electrophiles to produce an unprecedented array of η5-azaborolyl adducts (4) (substituents bound to boron: nitrogen, oxygen, hydrogen, carbon, and phosphorus).</abstract><pub>American Chemical Society</pub><doi>10.1021/om020533b</doi><tpages>3</tpages></addata></record> |
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title | The First General Method for the Synthesis of Transition-Metal π Complexes of an Electronically Diverse Family of 1,2-Azaborolyls |
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