Multiple C−H Bond Activation. Threefold-Deprotonated 6-Phenyl-2,2‘-bipyridine as a Bridging Ligand in Dinuclear Platinum(II) Derivatives

Multiple C−H Bond Activation. Threefold-Deprotonated 6-Phenyl-2,2‘-bipyridine as a Bridging Ligand in Dinuclear Platinum(II) Derivatives

Unusual platinum(II) trimetalated derivatives have been synthesized and characterized by reaction of cis-[Pt(R)2(DMSO)2] (R = Me, Ph) and 6-phenyl-2,2‘-bipyridine. The behavior of the substituted 2,2‘-bipyridine as a threefold-deprotonated ligand is unprecedented.

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Veröffentlicht in:Organometallics 2002-03, Vol.21 (5), p.783-785
Hauptverfasser: Zucca, Antonio, Doppiu, Angelino, Cinellu, Maria Agostina, Stoccoro, Sergio, Minghetti, Giovanni, Manassero, Mario
Format: Artikel
Sprache:eng
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Zusammenfassung:Unusual platinum(II) trimetalated derivatives have been synthesized and characterized by reaction of cis-[Pt(R)2(DMSO)2] (R = Me, Ph) and 6-phenyl-2,2‘-bipyridine. The behavior of the substituted 2,2‘-bipyridine as a threefold-deprotonated ligand is unprecedented.
ISSN:0276-7333
1520-6041
DOI:10.1021/om010913h