Formation and Crystal Structure of a Cationic Mono(cyclopentadienyl) Complex of Calcium, [(C5Me5)Ca(OPPh3)3]+I

Formation and Crystal Structure of a Cationic Mono(cyclopentadienyl) Complex of Calcium, [(C5Me5)Ca(OPPh3)3]+I

When the neutral Lewis base triphenylphosphine oxide reacts with (C5Me5)CaI(thf)2 in THF, the halide is displaced from the calcium to generate the stable cation [(C5Me5)Ca(OPPh3)3]+. The latter exhibits a “piano stool” geometry and displays only modest air sensitivity.

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Veröffentlicht in:Organometallics 2001-08, Vol.20 (17), p.3638-3640
Hauptverfasser: Jayaratne, Kumudini C, Fitts, Lacey S, Hanusa, Timothy P, Young, Victor G
Format: Artikel
Sprache:eng
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Zusammenfassung:When the neutral Lewis base triphenylphosphine oxide reacts with (C5Me5)CaI(thf)2 in THF, the halide is displaced from the calcium to generate the stable cation [(C5Me5)Ca(OPPh3)3]+. The latter exhibits a “piano stool” geometry and displays only modest air sensitivity.
ISSN:0276-7333
1520-6041
DOI:10.1021/om010399f