Metal-Catalyzed Hydroboration and Diboration of Thiocarbonyls and Vinyl Sulfides

α-Thioboronate esters are obtained directly in high yield and selectivity from metal-catalyzed additions of B−X bonds (X = H, B) to thiocarbonyl compounds and vinyl sulfides.

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Veröffentlicht in:Organometallics 2001-05, Vol.20 (11), p.2130-2132
Hauptverfasser: Carter, Charles A. G, Vogels, Christopher M, Harrison, Daniel J, Gagnon, M. Karen J, Norman, David W, Langler, Richard F, Baker, R. Thomas, Westcott, Stephen A
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container_end_page 2132
container_issue 11
container_start_page 2130
container_title Organometallics
container_volume 20
creator Carter, Charles A. G
Vogels, Christopher M
Harrison, Daniel J
Gagnon, M. Karen J
Norman, David W
Langler, Richard F
Baker, R. Thomas
Westcott, Stephen A
description α-Thioboronate esters are obtained directly in high yield and selectivity from metal-catalyzed additions of B−X bonds (X = H, B) to thiocarbonyl compounds and vinyl sulfides.
doi_str_mv 10.1021/om010135t
format Article
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title Metal-Catalyzed Hydroboration and Diboration of Thiocarbonyls and Vinyl Sulfides
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