Metal-Catalyzed Hydroboration and Diboration of Thiocarbonyls and Vinyl Sulfides

Metal-Catalyzed Hydroboration and Diboration of Thiocarbonyls and Vinyl Sulfides

α-Thioboronate esters are obtained directly in high yield and selectivity from metal-catalyzed additions of B−X bonds (X = H, B) to thiocarbonyl compounds and vinyl sulfides.

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Veröffentlicht in:Organometallics 2001-05, Vol.20 (11), p.2130-2132
Hauptverfasser: Carter, Charles A. G, Vogels, Christopher M, Harrison, Daniel J, Gagnon, M. Karen J, Norman, David W, Langler, Richard F, Baker, R. Thomas, Westcott, Stephen A
Format: Artikel
Sprache:eng
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Zusammenfassung:α-Thioboronate esters are obtained directly in high yield and selectivity from metal-catalyzed additions of B−X bonds (X = H, B) to thiocarbonyl compounds and vinyl sulfides.
ISSN:0276-7333
1520-6041
DOI:10.1021/om010135t