Synthesis, Structural Characterization, and Luminescence Properties of Branched Palladium(II) and Platinum(II) Acetylide Complexes

Synthesis, Structural Characterization, and Luminescence Properties of Branched Palladium(II) and Platinum(II) Acetylide Complexes

Three luminescent palladium(II) and platinum(II) acetylide complexes, 1,3-[Cl(PEt3)2PdC⋮CC6H4C⋮C]2-5-[( i Pr)3SiC⋮C]C6H3 and 1,3,5-[Cl(PEt3)2MC⋮CC6H4C⋮C]3C6H3 (M = Pd or Pt), have been synthesized by the reaction of the corresponding starting complexes, trans-M(PEt3)2Cl2 (M = Pd or Pt), with branche...

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Veröffentlicht in:Organometallics 2001-02, Vol.20 (3), p.453-459
Hauptverfasser: Yam, Vivian Wing-Wah, Tao, Chi-Hang, Zhang, Lingjun, Wong, Keith Man-Chung, Cheung, Kung-Kai
Format: Artikel
Sprache:eng
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Zusammenfassung:Three luminescent palladium(II) and platinum(II) acetylide complexes, 1,3-[Cl(PEt3)2PdC⋮CC6H4C⋮C]2-5-[( i Pr)3SiC⋮C]C6H3 and 1,3,5-[Cl(PEt3)2MC⋮CC6H4C⋮C]3C6H3 (M = Pd or Pt), have been synthesized by the reaction of the corresponding starting complexes, trans-M(PEt3)2Cl2 (M = Pd or Pt), with branched alkynyl ligands. Their crystal structures, together with their luminescence behavior, have been reported.
ISSN:0276-7333
1520-6041
DOI:10.1021/om000821c