Synthesis and Characterization of Soluble Poly(ferrocenylenearylene)s from Condensation of Dilithio Bis(alkylcyclopentadienide)arenes with Iron(II) Halides:  A General Route to Conjugated Poly(metallocene)s

Bis(alkylcyclopentadienyl)arenes have been prepared by sequential lithiation/alkylation of dibromoarenes with alkylcyclopenta-2-en-1-ones. The resulting dicarbinols were dehydrated with p-toluenesulfonic acid to give the bis(alkylcyclopentadienyl)arene. Poly(alkyl-1,1‘-ferrocenylenearylene)s were pr...

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Veröffentlicht in:Organometallics 2001-02, Vol.20 (3), p.508-522
Hauptverfasser: Southard, Glen E, Curtis, M. David
Format: Artikel
Sprache:eng
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