Synthesis and Characterization of Soluble Poly(ferrocenylenearylene)s from Condensation of Dilithio Bis(alkylcyclopentadienide)arenes with Iron(II) Halides:  A General Route to Conjugated Poly(metallocene)s

Bis(alkylcyclopentadienyl)arenes have been prepared by sequential lithiation/alkylation of dibromoarenes with alkylcyclopenta-2-en-1-ones. The resulting dicarbinols were dehydrated with p-toluenesulfonic acid to give the bis(alkylcyclopentadienyl)arene. Poly(alkyl-1,1‘-ferrocenylenearylene)s were pr...

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Veröffentlicht in:Organometallics 2001-02, Vol.20 (3), p.508-522
Hauptverfasser: Southard, Glen E, Curtis, M. David
Format: Artikel
Sprache:eng
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Zusammenfassung:Bis(alkylcyclopentadienyl)arenes have been prepared by sequential lithiation/alkylation of dibromoarenes with alkylcyclopenta-2-en-1-ones. The resulting dicarbinols were dehydrated with p-toluenesulfonic acid to give the bis(alkylcyclopentadienyl)arene. Poly(alkyl-1,1‘-ferrocenylenearylene)s were prepared by the reaction of dilithio bis(alkylcyclopentadienide)arenes and iron(II) salts in THF. The resulting polymers were oxidized with iodine to give the fully oxidized polyionomers. The polyionomers were found to give mixed-valence polymers when allowed to equilibrate with neutral polymers in solution, provided the degree of oxidation, N, lies between ca. 0.55 and 1.0. For degrees of oxidation 0.0 < N
ISSN:0276-7333
1520-6041
DOI:10.1021/om000722z