Synthesis and Characterization of Novel p-Phenylene- and p-Biphenylene-Bridged Germanocenes

New p-phenylene- and p-biphenylene-bridged germanocenes have been synthesized and characterized. An X-ray crystal structure reveals a bent-sandwich system. Their reactions with o-quinone and ferrocenium salt are reported.

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Veröffentlicht in:Organometallics 2000-11, Vol.19 (23), p.4678-4680
Hauptverfasser: Rouzaud, J, Castel, A, Rivière, P, Gornitzka, H, Manriquez, J. M
Format: Artikel
Sprache:eng
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Zusammenfassung:New p-phenylene- and p-biphenylene-bridged germanocenes have been synthesized and characterized. An X-ray crystal structure reveals a bent-sandwich system. Their reactions with o-quinone and ferrocenium salt are reported.
ISSN:0276-7333
1520-6041
DOI:10.1021/om000457h