Synthesis and structural characterization of a tetranuclear organolanthanide hydrazido complex
The authors describe the synthesis of a samarium cyclopentadienyl hydrazido complex. Cp*{sub 2}Sm (Cp* = {eta}{sup 5}-C{sub 5}Me{sub 5}) reacts with hydrazine giving the yellow crystalline product. Single-crystal diffraction was used to characterize the product. The molecule consists of distorted-te...
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| Veröffentlicht in: | Organometallics 1992-03, Vol.11 (3), p.1011-1013 |
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| container_title | Organometallics |
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| creator | Wang, Kuo Guang Stevens, Edwin D Nolan, Steven P |
| description | The authors describe the synthesis of a samarium cyclopentadienyl hydrazido complex. Cp*{sub 2}Sm (Cp* = {eta}{sup 5}-C{sub 5}Me{sub 5}) reacts with hydrazine giving the yellow crystalline product. Single-crystal diffraction was used to characterize the product. The molecule consists of distorted-tetrahedrons of samarium atoms bridged by hydrazido. 21 refs., 1 fig., 1 tab. |
| doi_str_mv | 10.1021/om00039a003 |
| format | Article |
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Cp*{sub 2}Sm (Cp* = {eta}{sup 5}-C{sub 5}Me{sub 5}) reacts with hydrazine giving the yellow crystalline product. Single-crystal diffraction was used to characterize the product. The molecule consists of distorted-tetrahedrons of samarium atoms bridged by hydrazido. 21 refs., 1 fig., 1 tab.</description><identifier>ISSN: 0276-7333</identifier><identifier>EISSN: 1520-6041</identifier><identifier>DOI: 10.1021/om00039a003</identifier><identifier>CODEN: ORGND7</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>40 CHEMISTRY ; CHEMICAL PREPARATION ; CHEMICAL REACTION YIELD ; Chemistry ; Condensed matter: structure, mechanical and thermal properties ; CRYSTAL STRUCTURE ; Exact sciences and technology ; HYDRAZIDES ; Miscellaneous ; Organic chemistry ; Organic compounds ; ORGANOMETALLIC COMPOUNDS ; Organometalloidal and organometallic compounds ; Physics ; Preparations and properties ; SAMARIUM COMPLEXES ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Organometallics, 1992-03, Vol.11 (3), p.1011-1013</ispartof><rights>1992 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a356t-6ec7636ea05aa46b1486621931ffdb33d07ba4b16faa933475b5517fbf5e5e783</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/om00039a003$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/om00039a003$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,885,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5217351$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/415023$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Kuo Guang</creatorcontrib><creatorcontrib>Stevens, Edwin D</creatorcontrib><creatorcontrib>Nolan, Steven P</creatorcontrib><title>Synthesis and structural characterization of a tetranuclear organolanthanide hydrazido complex</title><title>Organometallics</title><addtitle>Organometallics</addtitle><description>The authors describe the synthesis of a samarium cyclopentadienyl hydrazido complex. Cp*{sub 2}Sm (Cp* = {eta}{sup 5}-C{sub 5}Me{sub 5}) reacts with hydrazine giving the yellow crystalline product. Single-crystal diffraction was used to characterize the product. 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Cp*{sub 2}Sm (Cp* = {eta}{sup 5}-C{sub 5}Me{sub 5}) reacts with hydrazine giving the yellow crystalline product. Single-crystal diffraction was used to characterize the product. The molecule consists of distorted-tetrahedrons of samarium atoms bridged by hydrazido. 21 refs., 1 fig., 1 tab.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/om00039a003</doi><tpages>3</tpages></addata></record> |
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| ispartof | Organometallics, 1992-03, Vol.11 (3), p.1011-1013 |
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| language | eng |
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| source | American Chemical Society Journals |
| subjects | 40 CHEMISTRY CHEMICAL PREPARATION CHEMICAL REACTION YIELD Chemistry Condensed matter: structure, mechanical and thermal properties CRYSTAL STRUCTURE Exact sciences and technology HYDRAZIDES Miscellaneous Organic chemistry Organic compounds ORGANOMETALLIC COMPOUNDS Organometalloidal and organometallic compounds Physics Preparations and properties SAMARIUM COMPLEXES Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | Synthesis and structural characterization of a tetranuclear organolanthanide hydrazido complex |
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