Synthesis and structural characterization of a tetranuclear organolanthanide hydrazido complex

The authors describe the synthesis of a samarium cyclopentadienyl hydrazido complex. Cp*{sub 2}Sm (Cp* = {eta}{sup 5}-C{sub 5}Me{sub 5}) reacts with hydrazine giving the yellow crystalline product. Single-crystal diffraction was used to characterize the product. The molecule consists of distorted-te...

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Veröffentlicht in:	Organometallics 1992-03, Vol.11 (3), p.1011-1013
Hauptverfasser:	Wang, Kuo Guang, Stevens, Edwin D, Nolan, Steven P
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY CHEMICAL PREPARATION CHEMICAL REACTION YIELD Chemistry Condensed matter: structure, mechanical and thermal properties CRYSTAL STRUCTURE Exact sciences and technology HYDRAZIDES Miscellaneous Organic chemistry Organic compounds ORGANOMETALLIC COMPOUNDS Organometalloidal and organometallic compounds Physics Preparations and properties SAMARIUM COMPLEXES Structure of solids and liquids crystallography Structure of specific crystalline solids
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Zusammenfassung:	The authors describe the synthesis of a samarium cyclopentadienyl hydrazido complex. Cp{sub 2}Sm (Cp = {eta}{sup 5}-C{sub 5}Me{sub 5}) reacts with hydrazine giving the yellow crystalline product. Single-crystal diffraction was used to characterize the product. The molecule consists of distorted-tetrahedrons of samarium atoms bridged by hydrazido. 21 refs., 1 fig., 1 tab.
ISSN:	0276-7333 1520-6041
DOI:	10.1021/om00039a003