Two Trigonal Ni(silylene)3 Complexes
Two homoleptic Ni(silylene)3 complexes, 1a and 2a, have been synthesized and characterized by X-ray crystallography. Due to steric constraints only three silylenes coordinate to the nickel, generating novel complexes that are trigonal planar at the nickel center.
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| Veröffentlicht in: | Organometallics 2000-08, Vol.19 (17), p.3263-3265 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Two homoleptic Ni(silylene)3 complexes, 1a and 2a, have been synthesized and characterized by X-ray crystallography. Due to steric constraints only three silylenes coordinate to the nickel, generating novel complexes that are trigonal planar at the nickel center. |
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| ISSN: | 0276-7333 1520-6041 |
| DOI: | 10.1021/om000110e |