Stable Preformed Chiral Palladium Catalysts for the One-Pot Asymmetric Reductive Amination of Ketones

The application of air stable preformed [(R)-BINAP]PdBr2, [(S)-BINAP]PdBr2, [(R)-Tol-BINAP]PdBr2, and [(S,S)-CHIRAPHOS]PdBr2 complexes in the one-pot asymmetric reductive amination of various carbonyl compounds, leading to chiral amines in very good yields with high enantioselectivities (

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Veröffentlicht in:	Organic letters 2009-01, Vol.11 (2), p.265-268
Hauptverfasser:	Rubio-Pérez, Laura, Pérez-Flores, F. Javier, Sharma, Pankaj, Velasco, Luis, Cabrera, Armando
Format:	Artikel
Sprache:	eng
Schlagworte:	Air Amination Aniline Compounds - chemistry Catalysis Crystallography, X-Ray Hydrogen - chemistry Ketones - chemistry Oxidation-Reduction Palladium - chemistry Stereoisomerism
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description	The application of air stable preformed [(R)-BINAP]PdBr2, [(S)-BINAP]PdBr2, [(R)-Tol-BINAP]PdBr2, and [(S,S)-CHIRAPHOS]PdBr2 complexes in the one-pot asymmetric reductive amination of various carbonyl compounds, leading to chiral amines in very good yields with high enantioselectivities (
doi_str_mv	10.1021/ol802336m
format	Article
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Lett</addtitle><description>The application of air stable preformed [(R)-BINAP]PdBr2, [(S)-BINAP]PdBr2, [(R)-Tol-BINAP]PdBr2, and [(S,S)-CHIRAPHOS]PdBr2 complexes in the one-pot asymmetric reductive amination of various carbonyl compounds, leading to chiral amines in very good yields with high enantioselectivities (<99% ee), is reported.</description><subject>Air</subject><subject>Amination</subject><subject>Aniline Compounds - chemistry</subject><subject>Catalysis</subject><subject>Crystallography, X-Ray</subject><subject>Hydrogen - chemistry</subject><subject>Ketones - chemistry</subject><subject>Oxidation-Reduction</subject><subject>Palladium - chemistry</subject><subject>Stereoisomerism</subject><issn>1523-7060</issn><issn>1523-7052</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkEtPwzAQhC0EolA48AeQLxw4BNYxSeNjVfESlVrxOEcbe6OmSuLKdpD67zFqVS6cdjT6NNoZxq4E3AlIxb1tC0ilzLsjdiayVCYTyNLjg85hxM69XwOI6KhTNhIKlCxAnjH6CFi1xJeOaus6Mny2ahy2fIlti6YZOj7DgO3WB88jwcOK-KKnZGkDn_pt11FwjebvZAYdmm_i067pMTS257bmbxRsT_6CndTYerrc3zH7enr8nL0k88Xz62w6T1BOVEgMGKi1MWldIKkHASjrXGSFobwyWhBVRXQQjMBMKq0qKHIEWRU6rUFNcjlmt7tc7az3sVK5cU2HblsKKH-nKg9TRfZ6x26GKvb-I_fbROBmB6D25doOro-v_xP0A0sicbk</recordid><startdate>20090115</startdate><enddate>20090115</enddate><creator>Rubio-Pérez, Laura</creator><creator>Pérez-Flores, F. 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subjects	Air Amination Aniline Compounds - chemistry Catalysis Crystallography, X-Ray Hydrogen - chemistry Ketones - chemistry Oxidation-Reduction Palladium - chemistry Stereoisomerism
title	Stable Preformed Chiral Palladium Catalysts for the One-Pot Asymmetric Reductive Amination of Ketones
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