Synthesis and Controllable Self-Assembly of a Novel Coronene Bisimide Amphiphile

The synthesis of an amphiphilic coronene bisimide (Amph-CBI) and its self-assembly in THF/water through π−π stacking and solvophobic interactions are reported. Spectroscopic and microscopic studies revealed a bilayer like self-assembly of the coronene amphiphile to different kinds of one-dimensional...

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Veröffentlicht in:Organic letters 2010-06, Vol.12 (11), p.2656-2659
Hauptverfasser: Rao, K. Venkata, George, Subi J.
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George, Subi J.
description The synthesis of an amphiphilic coronene bisimide (Amph-CBI) and its self-assembly in THF/water through π−π stacking and solvophobic interactions are reported. Spectroscopic and microscopic studies revealed a bilayer like self-assembly of the coronene amphiphile to different kinds of one-dimensional nanostructures, such as nanotubes and nanotapes, which can be controlled by solvent composition.
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title Synthesis and Controllable Self-Assembly of a Novel Coronene Bisimide Amphiphile
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