Synthesis and Controllable Self-Assembly of a Novel Coronene Bisimide Amphiphile
The synthesis of an amphiphilic coronene bisimide (Amph-CBI) and its self-assembly in THF/water through π−π stacking and solvophobic interactions are reported. Spectroscopic and microscopic studies revealed a bilayer like self-assembly of the coronene amphiphile to different kinds of one-dimensional...
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| Veröffentlicht in: | Organic letters 2010-06, Vol.12 (11), p.2656-2659 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The synthesis of an amphiphilic coronene bisimide (Amph-CBI) and its self-assembly in THF/water through π−π stacking and solvophobic interactions are reported. Spectroscopic and microscopic studies revealed a bilayer like self-assembly of the coronene amphiphile to different kinds of one-dimensional nanostructures, such as nanotubes and nanotapes, which can be controlled by solvent composition. |
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| ISSN: | 1523-7060 1523-7052 |
| DOI: | 10.1021/ol100864e |