Thermal Isomerization of cis, a nti,cis-Tricyclo[6.3.0.02,7]undec-3-ene to e ndo-Tricyclo[5.2.2.02,6]undec-8-ene
The gas-phase thermal isomerization of cis,anti,cis-tricyclo[6.3.0.02,7]undec-3-ene (1) to endo-tricyclo[5.2.2.02,6]undec-8-ene (2) at 315 °C occurs cleanly through a symmetry-forbidden [1,3] suprafacial,retention (sr) pathway.
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| Veröffentlicht in: | Organic letters 2005-11, Vol.7 (23), p.5195-5197 |
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| container_end_page | 5197 |
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| container_issue | 23 |
| container_start_page | 5195 |
| container_title | Organic letters |
| container_volume | 7 |
| creator | Baldwin, John E Bogdan, Andrew R Leber, Phyllis A Powers, David C |
| description | The gas-phase thermal isomerization of cis,anti,cis-tricyclo[6.3.0.02,7]undec-3-ene (1) to endo-tricyclo[5.2.2.02,6]undec-8-ene (2) at 315 °C occurs cleanly through a symmetry-forbidden [1,3] suprafacial,retention (sr) pathway. |
| doi_str_mv | 10.1021/ol052004k |
| format | Article |
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| ispartof | Organic letters, 2005-11, Vol.7 (23), p.5195-5197 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1021_ol052004k |
| source | ACS Publications |
| title | Thermal Isomerization of cis, a nti,cis-Tricyclo[6.3.0.02,7]undec-3-ene to e ndo-Tricyclo[5.2.2.02,6]undec-8-ene |
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