Thermal Isomerization of cis, a nti,cis-Tricyclo[6.3.0.02,7]undec-3-ene to e ndo-Tricyclo[5.2.2.02,6]undec-8-ene
The gas-phase thermal isomerization of cis,anti,cis-tricyclo[6.3.0.02,7]undec-3-ene (1) to endo-tricyclo[5.2.2.02,6]undec-8-ene (2) at 315 °C occurs cleanly through a symmetry-forbidden [1,3] suprafacial,retention (sr) pathway.
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| Veröffentlicht in: | Organic letters 2005-11, Vol.7 (23), p.5195-5197 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The gas-phase thermal isomerization of cis,anti,cis-tricyclo[6.3.0.02,7]undec-3-ene (1) to endo-tricyclo[5.2.2.02,6]undec-8-ene (2) at 315 °C occurs cleanly through a symmetry-forbidden [1,3] suprafacial,retention (sr) pathway. |
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| ISSN: | 1523-7060 1523-7052 |
| DOI: | 10.1021/ol052004k |