Twist-Dependent Electronic Coupling in an Organic Intervalence Radical Cation

Twist-Dependent Electronic Coupling in an Organic Intervalence Radical Cation

The nearly 90° twist between the reduced dialkylaniline π system and the oxygen atom p lone pair orbital limits electronic interaction between the reduced and oxidized aniline units and makes varying this twist angle a principal factor that facilitates intramolecular electron transfer.

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Veröffentlicht in:Organic letters 2001-05, Vol.3 (10), p.1583-1586
Hauptverfasser: Nelsen, Stephen F, Li, Gaoquan, Konradsson, Asgeir
Format: Artikel
Sprache:eng
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Zusammenfassung:The nearly 90° twist between the reduced dialkylaniline π system and the oxygen atom p lone pair orbital limits electronic interaction between the reduced and oxidized aniline units and makes varying this twist angle a principal factor that facilitates intramolecular electron transfer.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol015874k