Configurational Ordering of Cationic Chiral Dyes Using a Novel C 2-Symmetric Hexacoordinated Phosphate Anion

Configurational Ordering of Cationic Chiral Dyes Using a Novel C 2-Symmetric Hexacoordinated Phosphate Anion

C 2-Symmetry hexacoordinated phosphorus BINPHAT anionof configuration controlled by a BINOL ligandcan be prepared readily in a one-pot process and behaves as an efficient NMR chiral shift agent and chiral inducer onto monomethinium dyes (CD, 1H NMR).

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Veröffentlicht in:Organic letters 2000-12, Vol.2 (26), p.4185-4188
Hauptverfasser: Lacour, Jérôme, Londez, Anne, Goujon-Ginglinger, Catherine, Buss, Volker, Bernardinelli, Gérald
Format: Artikel
Sprache:eng
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Zusammenfassung:C 2-Symmetry hexacoordinated phosphorus BINPHAT anionof configuration controlled by a BINOL ligandcan be prepared readily in a one-pot process and behaves as an efficient NMR chiral shift agent and chiral inducer onto monomethinium dyes (CD, 1H NMR).
ISSN:1523-7060
1523-7052
DOI:10.1021/ol006731l