Heck Reactions Catalyzed by PAMAM-Dendrimer Encapsulated Pd(0) Nanoparticles

The behavior of PAMAM-dendrimer encapsulated palladium nanoparticles as catalysts for the Heck reaction has been examined, and it has been demonstrated that this simple system is a very efficient catalyst giving good yields under phosphine-free conditions and with 200−400 times less Pd than usual.

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Veröffentlicht in:Nano letters 2001-09, Vol.1 (9), p.499-501
Hauptverfasser: Rahim, Enaam H, Kamounah, Fadhil S, Frederiksen, John, Christensen, Jørn B
Format: Artikel
Sprache:eng
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Zusammenfassung:The behavior of PAMAM-dendrimer encapsulated palladium nanoparticles as catalysts for the Heck reaction has been examined, and it has been demonstrated that this simple system is a very efficient catalyst giving good yields under phosphine-free conditions and with 200−400 times less Pd than usual.
ISSN:1530-6984
1530-6992
DOI:10.1021/nl015574w