Rigid-Rod Polyimides Based on Noncoplanar 4,4‘-Biphenyldiamines: A Review of Polymer Properties vs Configuration of Diamines

X-ray crystal structures of three substituted 4,4‘-biphenyldiamines, namely, 2,2‘,6,6‘-tetramethylbenzidine (TMBZ), 2,2‘-dimethylbenzidine (DMBZ) and 2,2‘-bis(trifluoromethyl)benzidine (BFBZ), were determined. The torsional angles between the two phenyl rings for TMBZ, DMBZ, and BFBZ are φ = 83°, 75...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Macromolecules 1997-11, Vol.30 (23), p.7183-7190
Hauptverfasser:	Chuang, Kathy C, Kinder, James D, Hull, Diana L, McConville, David B, Youngs, Wiley J
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization Structure, morphology and analysis
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	X-ray crystal structures of three substituted 4,4‘-biphenyldiamines, namely, 2,2‘,6,6‘-tetramethylbenzidine (TMBZ), 2,2‘-dimethylbenzidine (DMBZ) and 2,2‘-bis(trifluoromethyl)benzidine (BFBZ), were determined. The torsional angles between the two phenyl rings for TMBZ, DMBZ, and BFBZ are φ = 83°, 75°, and 59°, respectively. A structure−property relationship between the three-dimensional configuration of diamine monomers and the corresponding polyimides is discussed.
ISSN:	0024-9297 1520-5835
DOI:	10.1021/ma970309b