Near-Infrared Electrochromic and Electroluminescent Polymers Containing Pendant Ruthenium Complex Groups

A series of near-infrared (NIR) electrochromic and electroluminescent polymers containing the pendant dinuclear ruthenium complexes were synthesized and characterized. All the polymers are near-infrared (NIR) electrochromic, displaying an intense absorption centered at 1600 nm upon oxidation to the...

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Veröffentlicht in:	Macromolecules 2006-10, Vol.39 (22), p.7502-7507
Hauptverfasser:	Wang, Sheng, Li, Xianzhen, Xun, Shidi, Wan, Xinhua, Wang, Zhi Yuan
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts
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Zusammenfassung:	A series of near-infrared (NIR) electrochromic and electroluminescent polymers containing the pendant dinuclear ruthenium complexes were synthesized and characterized. All the polymers are near-infrared (NIR) electrochromic, displaying an intense absorption centered at 1600 nm upon oxidation to the mixed-valence state. Single-layer diode devices comprising a layer of the complex polymers sandwiched between the ITO and Au electrodes emitted the NIR light centered at 790 nm at ambient temperature.
ISSN:	0024-9297 1520-5835
DOI:	10.1021/ma061751+