Directed Reactions within Confined Reaction Environments:  Polyadditions in Polyelectrolyte−Surfactant Complexes

Directed Reactions within Confined Reaction Environments:  Polyadditions in Polyelectrolyte−Surfactant Complexes

Polyaddition reactions performed within a highly ordered polyelectrolyte−surfactant monomer complex of polydiallyldimethylammonium chloride and di(undecenyl) phosphate give a 1:1 copy of the original lamellar host structure. No phase disruption or disordering occurs during the reaction. The phase mo...

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Veröffentlicht in:Macromolecules 2003-04, Vol.36 (8), p.2862-2866
Hauptverfasser: Ganeva, Desislava, Faul, Charl F. J, Götz, Christian, Sanderson, Ronald D
Format: Artikel
Sprache:eng
Schlagworte:
Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Special properties (catalyst, reagent or carrier)
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Beschreibung
Zusammenfassung:Polyaddition reactions performed within a highly ordered polyelectrolyte−surfactant monomer complex of polydiallyldimethylammonium chloride and di(undecenyl) phosphate give a 1:1 copy of the original lamellar host structure. No phase disruption or disordering occurs during the reaction. The phase morphology of the host before and after swelling and after polymerization is investigated by small-angle-X-ray scattering and transmission electron microscopy. The polymer symplex has an improved thermal and mechanical stability.
ISSN:0024-9297
1520-5835
DOI:10.1021/ma021136f