Synthesis and Nonlinear Optical Properties of a New Syndioregic Main-Chain Hydrazone Polymer

The synthesis of a syndioregic main-chain hydrazone nonlinear optical polymer is reported. The nonlinearity is thermally stable up to 140 °C and retains 90% of the original value even when stored at 100 °C for 100 h. The polymer has a relatively low nonlinearity (d 33 = 3.6 pm/V) due to the incorpor...

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Veröffentlicht in:	Macromolecules 2001-02, Vol.34 (5), p.1493-1495
Hauptverfasser:	Hayden, L. Michael, Kim, Won-Kook, Chafin, Andrew P, Lindsay, Geoffrey A
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts
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Zusammenfassung:	The synthesis of a syndioregic main-chain hydrazone nonlinear optical polymer is reported. The nonlinearity is thermally stable up to 140 °C and retains 90% of the original value even when stored at 100 °C for 100 h. The polymer has a relatively low nonlinearity (d 33 = 3.6 pm/V) due to the incorporation of a low β chromophore.
ISSN:	0024-9297 1520-5835
DOI:	10.1021/ma001796p