Phosphorolytic Cleavage of Phosphate and Phosphonoformate Diesters by Cetyltrimethylammonium Iodosobenzoate

Phosphorolytic Cleavage of Phosphate and Phosphonoformate Diesters by Cetyltrimethylammonium Iodosobenzoate

Micellar cetyltrimethylammonium iodosobenzoate (4) cleaves P−O ester linkages of bis(p-nitrophenyl) phosphate (3), methoxycarbonyl phenyl phosphonoformate (6), and hexyloxycarbonyl phenyl phosphonoformate (7). Kinetic advantages of several orders of magnitude are obtained relative to the unassisted...

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Veröffentlicht in:Langmuir 2002-04, Vol.18 (7), p.2468-2470
Hauptverfasser: Moss, Robert A, Vijayaraghavan, Saketh, Kanamathareddy, Suseela
Format: Artikel
Sprache:eng
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Zusammenfassung:Micellar cetyltrimethylammonium iodosobenzoate (4) cleaves P−O ester linkages of bis(p-nitrophenyl) phosphate (3), methoxycarbonyl phenyl phosphonoformate (6), and hexyloxycarbonyl phenyl phosphonoformate (7). Kinetic advantages of several orders of magnitude are obtained relative to the unassisted hydrolyses.
ISSN:0743-7463
1520-5827
DOI:10.1021/la0116488