Screening in Short Polyelectrolyte Chains. A Monte Carlo Study

A general definition of effective screening in a polyelectrolyte chain is introduced to replace the definition formulated in a previous article. Using the new definition it is shown that the number of chain beads N affects screening at the investigated range of N. Additional evidence to our concept...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of physical chemistry (1952) 1996-10, Vol.100 (44), p.17563-17567
Hauptverfasser: Brender, Chava, Danino, Meir
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A general definition of effective screening in a polyelectrolyte chain is introduced to replace the definition formulated in a previous article. Using the new definition it is shown that the number of chain beads N affects screening at the investigated range of N. Additional evidence to our concept of equivalence of polyelectrolyte chains with added salt and partially charged bare chains is demonstrated by means of various parameters. Comparison of configurations obtained by different means is considered as well as which parameters are sufficient for the comparison.
ISSN:0022-3654
1541-5740
DOI:10.1021/jp951368z