Resonant Inelastic X‑ray Scattering of Molybdenum Oxides and Sulfides
Molybdenum oxides and sulfides were studied using resonant inelastic X-ray scattering (RIXS). The 2p3/23d Mo RIXS planes show a rich structure with considerably more spectral information than in conventional X-ray absorption near edge structure (XANES) spectroscopy. The spectra were simulated using...
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Veröffentlicht in: | Journal of physical chemistry. C 2015-02, Vol.119 (5), p.2419-2426 |
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Hauptverfasser: | , , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | Molybdenum oxides and sulfides were studied using resonant inelastic X-ray scattering (RIXS). The 2p3/23d Mo RIXS planes show a rich structure with considerably more spectral information than in conventional X-ray absorption near edge structure (XANES) spectroscopy. The spectra were simulated using FEFF9 giving generally good agreement and detailed electronic information can be derived. The reference materials serve as a starting point for detailed electronic and geometric investigations of a broad range of compounds. In particular, this can provide insights in the properties and performance of unknown and changing materials like those in catalysis. |
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ISSN: | 1932-7447 1932-7455 |
DOI: | 10.1021/jp509376q |