Facile Fabrication of 3D-Ordered Macroporous Nanocrystalline Iron Oxide Films with Highly Efficient Visible Light Induced Photocatalytic Activity

A facile approach of layer-by-layer depositing and hydrolysis of FeCl3 is developed to fabricate 3D-ordered Fe2O3 film. The 3D-ordered Fe2O3 film was characterized by SEM, XRD, and DRUV−vis. It has 3D-ordered interconnecting macropores (340 nm) with nanocrystalline hematite Fe2O3 walls (27.2 nm). The 3D-ordered macroporous nanocrystalline Fe2O3 film exhibits 2.4 times larger photocatalytic activity for the photodegradation of dye in the presence of H2O2 under visible irradiation than the nanocrystalline α-Fe2O3 film without macropores and very good photostability. The much higher photocatalytic activity of the 3D-ordered macroporous nanocrystalline Fe2O3 film than that of the reference Fe2O3 film is attributed to the unique nanostructure and architecture of the 3D-ordered Fe2O3 film, which result in the much greater light harvesting efficiency and efficient mass transport in the former than in the latter due to the existence of 3D-ordered interconnecting macropores. The effect of photonic stop band on the photocatalytic activity of the 3D-ordered Fe2O3 film was studied by angle-dependent solid-state photodegradation experiments with monochromatic irradiation. A slow photon enhancement of photocatalytic activity was achieved by adjusting the red edge of the photonic stop band of the 3D-ordered Fe2O3 film close to the electronic bandgap of Fe2O3. The photodegradation mechanism of crystal violet on the 3D-ordered Fe2O3 photocatalyst in the presence or absence of H2O2 was discussed.