Blackbody Infrared Radiative Dissociation of Partially Solvated Mixed Ligand Ru(II) Complex Ions

Blackbody Infrared Radiative Dissociation of Partially Solvated Mixed Ligand Ru(II) Complex Ions

Unimolecular dissociation reactions of gas-phase partially solvated transition metal complex ions, diamminebis(2,2‘-bipyridine)ruthenium(II), [Ru(NH3)2(bipy)2]2+, tetraammine(2,2‘-bipyridine)ruthenium(II), [Ru(NH3)4bipy]2+, and pentaammine(2-methylpyrazine)ruthenium(II), [Ru(NH3)5MePyz]3+, have been...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2004-11, Vol.108 (45), p.9892-9900
Hauptverfasser: Stevens, Stanley M, Dunbar, Robert C, Price, William D, Sena, Marcelo, Watson, Clifford H, Nichols, Linda S, Riveros, Jose M, Richardson, David E, Eyler, John R
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Sprache:eng
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Zusammenfassung:Unimolecular dissociation reactions of gas-phase partially solvated transition metal complex ions, diamminebis(2,2‘-bipyridine)ruthenium(II), [Ru(NH3)2(bipy)2]2+, tetraammine(2,2‘-bipyridine)ruthenium(II), [Ru(NH3)4bipy]2+, and pentaammine(2-methylpyrazine)ruthenium(II), [Ru(NH3)5MePyz]3+, have been investigated with electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI−FTICR/MS) under low pressure (
ISSN:1089-5639
1520-5215
DOI:10.1021/jp0484377