On the Construction of Particle Distributions with Specified Single and Pair Densities
We discuss necessary conditions for the existence of a probability distribution on particle configurations in d-dimensions, i.e., a point process, compatible with a specified density ρ and radial distribution function g(r). In d = 1 we give necessary and sufficient criteria on ρg(r) for the existenc...
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Veröffentlicht in: | The journal of physical chemistry. B 2004-12, Vol.108 (51), p.19614-19618 |
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description | We discuss necessary conditions for the existence of a probability distribution on particle configurations in d-dimensions, i.e., a point process, compatible with a specified density ρ and radial distribution function g(r). In d = 1 we give necessary and sufficient criteria on ρg(r) for the existence of such a point process of renewal (Markov) type. We prove that these conditions are satisfied for the case g(r) = 0, r < D and g(r) = 1, r > D, if and only if ρD ≤ e -1: the maximum density obtainable from diluting a Poisson process. We then describe briefly necessary and sufficient conditions, valid in every dimension, for ρg(r) to specify a determinantal point process for which all n-particle densities,ρ n (r 1,...,r n ), are given explicitly as determinants. We give several examples. |
doi_str_mv | 10.1021/jp047793m |
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L</creatorcontrib><title>On the Construction of Particle Distributions with Specified Single and Pair Densities</title><title>The journal of physical chemistry. B</title><addtitle>J. Phys. Chem. B</addtitle><description>We discuss necessary conditions for the existence of a probability distribution on particle configurations in d-dimensions, i.e., a point process, compatible with a specified density ρ and radial distribution function g(r). In d = 1 we give necessary and sufficient criteria on ρg(r) for the existence of such a point process of renewal (Markov) type. We prove that these conditions are satisfied for the case g(r) = 0, r < D and g(r) = 1, r > D, if and only if ρD ≤ e -1: the maximum density obtainable from diluting a Poisson process. We then describe briefly necessary and sufficient conditions, valid in every dimension, for ρg(r) to specify a determinantal point process for which all n-particle densities,ρ n (r 1,...,r n ), are given explicitly as determinants. 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B</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Costin, O</au><au>Lebowitz, J. L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>On the Construction of Particle Distributions with Specified Single and Pair Densities</atitle><jtitle>The journal of physical chemistry. B</jtitle><addtitle>J. Phys. Chem. B</addtitle><date>2004-12-23</date><risdate>2004</risdate><volume>108</volume><issue>51</issue><spage>19614</spage><epage>19618</epage><pages>19614-19618</pages><issn>1520-6106</issn><eissn>1520-5207</eissn><abstract>We discuss necessary conditions for the existence of a probability distribution on particle configurations in d-dimensions, i.e., a point process, compatible with a specified density ρ and radial distribution function g(r). In d = 1 we give necessary and sufficient criteria on ρg(r) for the existence of such a point process of renewal (Markov) type. We prove that these conditions are satisfied for the case g(r) = 0, r < D and g(r) = 1, r > D, if and only if ρD ≤ e -1: the maximum density obtainable from diluting a Poisson process. We then describe briefly necessary and sufficient conditions, valid in every dimension, for ρg(r) to specify a determinantal point process for which all n-particle densities,ρ n (r 1,...,r n ), are given explicitly as determinants. We give several examples.</abstract><pub>American Chemical Society</pub><doi>10.1021/jp047793m</doi><tpages>5</tpages></addata></record> |
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title | On the Construction of Particle Distributions with Specified Single and Pair Densities |
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