Effect of Water Vapor on the Combination and Disproportionation of Ethyl Radicals in the Gas Phase
The role of H2O vapor on the disproportionation/combination ratio (k d/k c) of C2H5 radical reactions in the gas phase has been investigated experimentally and compared to that observed previously in aqueous solution. At added water pressures of 20 kPa (15 Torr), the k d/k c ratio remains unchanged...
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| Veröffentlicht in: | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2004-03, Vol.108 (10), p.1638-1639 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The role of H2O vapor on the disproportionation/combination ratio (k d/k c) of C2H5 radical reactions in the gas phase has been investigated experimentally and compared to that observed previously in aqueous solution. At added water pressures of 20 kPa (15 Torr), the k d/k c ratio remains unchanged from that observed in its absence. The relationship of the invariant ratio to bonding and solvation phenomena are discussed. |
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| ISSN: | 1089-5639 1520-5215 |
| DOI: | 10.1021/jp040048p |