Spontaneous Formation of Cellular Chemical System that Sustains Itself far from Thermodynamic Equilibrium

We report the observation of the spontaneous formation of a cellular structure in a simple inorganic system. The system is obtained by immersing a pellet of calcium and copper chlorides in an alkali solution containing sodium carbonate, sodium iodide, and hydrogen peroxide. The system produces a cel...

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Veröffentlicht in:The journal of physical chemistry. B 2004-04, Vol.108 (16), p.4937-4939
Hauptverfasser: Maselko, Jerzy, Strizhak, Peter
Format: Artikel
Sprache:eng
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Zusammenfassung:We report the observation of the spontaneous formation of a cellular structure in a simple inorganic system. The system is obtained by immersing a pellet of calcium and copper chlorides in an alkali solution containing sodium carbonate, sodium iodide, and hydrogen peroxide. The system produces a cell surrounded by a semipermeable membrane. Reactants diffuse and react inside the cell with copper ions serving as catalyst. The products diffuse out of the cell. The system sustains itself far from thermodynamic equilibrium.
ISSN:1520-6106
1520-5207
DOI:10.1021/jp036417j