Synthesis of (−)-3-Amino-3-deoxyquinic Acid
An efficient synthesis of 3-amino-3-deoxyquinic acid, starting from (−)-quinic acid, is reported and its importance for the biosynthesis of 3-amino-5-hydroxybenzoic acid, the precursor of mC7N-units in ansamycin and mitomycin antibiotics is discussed.
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| Veröffentlicht in: | Journal of organic chemistry 1998-12, Vol.63 (26), p.9753-9755 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | An efficient synthesis of 3-amino-3-deoxyquinic acid, starting from (−)-quinic acid, is reported and its importance for the biosynthesis of 3-amino-5-hydroxybenzoic acid, the precursor of mC7N-units in ansamycin and mitomycin antibiotics is discussed. |
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| ISSN: | 0022-3263 1520-6904 |
| DOI: | 10.1021/jo981291l |