Analysis of kinetic isotope effects on complex reactions utilizing the concept of the virtual transition state

Analysis of kinetic isotope effects on complex reactions utilizing the concept of the virtual transition state

A procedure for the analysis of observed isotope effects on rates of complex reactions is outlined which can be applied to kinetic isotope effect data for any reaction having a virtual transition state whose structure can be varied by adjusting a reaction parameter. This procedure is applied to the...

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Veröffentlicht in:J. Org. Chem.; (United States) 1981-07, Vol.46 (16), p.3328-3330
1. Verfasser: Stein, Ross L
Format: Artikel
Sprache:eng
Schlagworte:
400302 - Organic Chemistry- Isotope Effects- (-1987)
AROMATICS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DATA ANALYSIS
DECOMPOSITION
DEUTERIUM
HYDROGEN ISOTOPES
HYDROLYSIS
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
ISOTOPE EFFECTS
ISOTOPES
KINETICS
LIGHT NUCLEI
LYSIS
NITRO COMPOUNDS
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
REACTION KINETICS
SOLVOLYSIS
STABLE ISOTOPES
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Beschreibung
Zusammenfassung:A procedure for the analysis of observed isotope effects on rates of complex reactions is outlined which can be applied to kinetic isotope effect data for any reaction having a virtual transition state whose structure can be varied by adjusting a reaction parameter. This procedure is applied to the basic hydrolysis of p-nitroacetanilide. 3 tables. (DLC)
ISSN:0022-3263
1520-6904
DOI:10.1021/jo00329a036