Synthesis and Properties of Tetrathiadiazafulvalenes [RCNS2C:CS2NCR] (R = H, Me, Ph)

Diazahexathioorthooxalate derivatives [RCNS{sub 2}C=CS{sub 2}NCR] (2, R = H, Me, Ph) can be synthesized in good yield from corresponding 5-(methylthio)-1,4,2-dithiazolium (3, R = H, Me, Ph) salts by reduction with zinc. The product tetrathiadiazafulvalenes were characterized by ESR and cyclic voltam...

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Veröffentlicht in:	Journal of Organic Chemistry 1994-06, Vol.59 (11), p.2997-3002
Hauptverfasser:	Oakley, Richard T, Richardson, John F, Spence, Rupert E. v. H
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY Aminoacids and peptides CHEMICAL PREPARATION CHEMICAL REACTION YIELD Chemistry Condensed matter: structure, mechanical and thermal properties ELECTRON SPIN RESONANCE Exact sciences and technology HETEROCYCLIC COMPOUNDS Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms Organic chemistry Organic compounds ORGANIC NITROGEN COMPOUNDS ORGANIC SULFUR COMPOUNDS OXIDATION Physics Preparations and properties RADICALS REDUCTION Structure of solids and liquids crystallography Structure of specific crystalline solids VOLTAMETRY
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Zusammenfassung:	Diazahexathioorthooxalate derivatives [RCNS{sub 2}C=CS{sub 2}NCR] (2, R = H, Me, Ph) can be synthesized in good yield from corresponding 5-(methylthio)-1,4,2-dithiazolium (3, R = H, Me, Ph) salts by reduction with zinc. The product tetrathiadiazafulvalenes were characterized by ESR and cyclic voltammetry.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo00090a016