A cobalt-phosphine complex as mediator in the formation of carbon-carbon bonds

The complex, [Co(P(CH{sub 3}){sub 3}){sub 4}], is found to mediate the Reformatsky-type reaction of halogenated esters, lactones, or amides with carbonyl compounds (ketones, aldehydes). The products of these reactions are alcohols. 15 refs., 1 tab.

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Veröffentlicht in:	Journal of Organic Chemistry 1994-01, Vol.59 (1), p.1-3
Hauptverfasser:	Orsini, Fulvia, Pelizzoni, Francesca, Pulici, Maurizio, Vallarino, Lidia M
Format:	Artikel
Sprache:	eng
Schlagworte:	10 SYNTHETIC FUELS 40 CHEMISTRY ALDEHYDES AMIDES CHEMICAL REACTIONS Chemistry COBALT COMPLEXES ESTERS Exact sciences and technology KETONES LACTONES ORGANIC BROMINE COMPOUNDS Organic chemistry ORGANIC CHLORINE COMPOUNDS
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Zusammenfassung:	The complex, [Co(P(CH{sub 3}){sub 3}){sub 4}], is found to mediate the Reformatsky-type reaction of halogenated esters, lactones, or amides with carbonyl compounds (ketones, aldehydes). The products of these reactions are alcohols. 15 refs., 1 tab.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo00080a001