Flow Injection System with Multisite Detection for Spectrophotometric Determination of Calcium and Magnesium in Soil Extracts and Natural Waters

A flow system with a relocatable detector for spectrophotometric determination of calcium (Ca) and magnesium (Mg) in KCl soil extracts and natural waters is presented. O-Cresolphthalein complexon (CPC) was selected as the chromogenic reagent, ammonium-ammonia as the buffer system, and EGTA or 8-hydr...

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Veröffentlicht in:Journal of agricultural and food chemistry 1996-01, Vol.44 (1), p.165-169
Hauptverfasser: Nogueira, Ana Rita A, Brienza, Sandra M. B, Zagatto, Elias A. G, Lima, José L. F. C, Araújo, Alberto N
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Sprache:eng
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Zusammenfassung:A flow system with a relocatable detector for spectrophotometric determination of calcium (Ca) and magnesium (Mg) in KCl soil extracts and natural waters is presented. O-Cresolphthalein complexon (CPC) was selected as the chromogenic reagent, ammonium-ammonia as the buffer system, and EGTA or 8-hydroxyquinoline as the masking agents for Ca or Mg, respectively. Linearity of the calibration equations was observed for Ca and Mg concentrations up to 80.0 and 15.0 mg/L, respectively. Slight variations in the coefficients of the calibration equations (usually
ISSN:0021-8561
1520-5118
DOI:10.1021/jf950168h