Method for the Production and Characterization of Tomato Cutin Oligomers
A series of oligomeric fragments can be obtained by partial alkaline hydrolysis of cutin. The oligomers obtained from tomato cutin were analyzed by high-performance liquid chromatography-mass spectrometry and the major products were characterized as linear dimeric esters of omega,8-, omega,9-, and o...
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Veröffentlicht in: | Journal of agricultural and food chemistry 1995-08, Vol.43 (8), p.2134-2137 |
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container_title | Journal of agricultural and food chemistry |
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creator | Osman, Stanley F Gerard, Herve C Fett, William F Moreau, Robert A Dudley, Robert L |
description | A series of oligomeric fragments can be obtained by partial alkaline hydrolysis of cutin. The oligomers obtained from tomato cutin were analyzed by high-performance liquid chromatography-mass spectrometry and the major products were characterized as linear dimeric esters of omega,8-, omega,9-, and omega,10-dihydroxyhexadecanoic acids, the major monomers of tomato cutin. Analysis of the products obtained from tomato cutin by treatment with cutinase suggests an exo mode of depolymerization for this enzyme |
doi_str_mv | 10.1021/jf00056a033 |
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The oligomers obtained from tomato cutin were analyzed by high-performance liquid chromatography-mass spectrometry and the major products were characterized as linear dimeric esters of omega,8-, omega,9-, and omega,10-dihydroxyhexadecanoic acids, the major monomers of tomato cutin. Analysis of the products obtained from tomato cutin by treatment with cutinase suggests an exo mode of depolymerization for this enzyme</description><identifier>ISSN: 0021-8561</identifier><identifier>EISSN: 1520-5118</identifier><identifier>DOI: 10.1021/jf00056a033</identifier><identifier>CODEN: JAFCAU</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>ACTIVIDAD ENZIMATICA ; ACTIVITE ENZYMATIQUE ; Agronomy. Soil science and plant productions ; BEURRE VEGETAL ; Biological and medical sciences ; Chemical constitution ; Economic plant physiology ; ESPECTROMETRIA DE MASAS ; ESTER ; ESTERASAS ; ESTERASE ; ESTERES ; ESTRUCTURA QUIMICA ; Fundamental and applied biological sciences. 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Agric. Food Chem</addtitle><description>A series of oligomeric fragments can be obtained by partial alkaline hydrolysis of cutin. The oligomers obtained from tomato cutin were analyzed by high-performance liquid chromatography-mass spectrometry and the major products were characterized as linear dimeric esters of omega,8-, omega,9-, and omega,10-dihydroxyhexadecanoic acids, the major monomers of tomato cutin. Analysis of the products obtained from tomato cutin by treatment with cutinase suggests an exo mode of depolymerization for this enzyme</description><subject>ACTIVIDAD ENZIMATICA</subject><subject>ACTIVITE ENZYMATIQUE</subject><subject>Agronomy. Soil science and plant productions</subject><subject>BEURRE VEGETAL</subject><subject>Biological and medical sciences</subject><subject>Chemical constitution</subject><subject>Economic plant physiology</subject><subject>ESPECTROMETRIA DE MASAS</subject><subject>ESTER</subject><subject>ESTERASAS</subject><subject>ESTERASE</subject><subject>ESTERES</subject><subject>ESTRUCTURA QUIMICA</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>GRASAS VEGETALES</subject><subject>HIDROLISIS</subject><subject>HPLC</subject><subject>HYDROLYSE</subject><subject>LYCOPERSICON ESCULENTUM</subject><subject>SPECTROMETRIE DE MASSE</subject><subject>STRUCTURE CHIMIQUE</subject><issn>0021-8561</issn><issn>1520-5118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1995</creationdate><recordtype>article</recordtype><recordid>eNptkE1LAzEQhoMoWKsnb55yEDzIarJJ9uMoxbZiSwvdnsNsNmm3tpuSbEH99UZXigdPA_M88zK8CF1T8kBJTB83hhAiEiCMnaAeFTGJBKXZKeqRgKNMJPQcXXi_CVomUtJD46lu17bCxjrcrjWeO1sdVFvbBkNT4cEaHKhWu_oTfpbW4MLuoLV4cGjrBs-29crutPOX6MzA1uur39lHy-FzMRhHk9noZfA0iYDxvI14mXMCpOSqynJdJbRMidHG5IYrUfLwZcUMrygnKeexZrrimeGEUZqmTGUJ66P7Llc5673TRu5dvQP3ISmR3yXIPyUE-7az9-AVbI2DRtX-eMISEWeCBi3qtNq3-v2Iwb3JJGWpkMV8IfloOixeJyOZB_-m8w1YCSsXIpeLPOWZ4HGAdx0E5eXGHlwT-vj3uy-PY38K</recordid><startdate>19950801</startdate><enddate>19950801</enddate><creator>Osman, Stanley F</creator><creator>Gerard, Herve C</creator><creator>Fett, William F</creator><creator>Moreau, Robert A</creator><creator>Dudley, Robert L</creator><general>American Chemical Society</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19950801</creationdate><title>Method for the Production and Characterization of Tomato Cutin Oligomers</title><author>Osman, Stanley F ; Gerard, Herve C ; Fett, William F ; Moreau, Robert A ; Dudley, Robert L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a349t-4b940a0b4cd89ed61b70feff9f4c5b4021d3f4d1407442e3ed48f40311773c863</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1995</creationdate><topic>ACTIVIDAD ENZIMATICA</topic><topic>ACTIVITE ENZYMATIQUE</topic><topic>Agronomy. Soil science and plant productions</topic><topic>BEURRE VEGETAL</topic><topic>Biological and medical sciences</topic><topic>Chemical constitution</topic><topic>Economic plant physiology</topic><topic>ESPECTROMETRIA DE MASAS</topic><topic>ESTER</topic><topic>ESTERASAS</topic><topic>ESTERASE</topic><topic>ESTERES</topic><topic>ESTRUCTURA QUIMICA</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>GRASAS VEGETALES</topic><topic>HIDROLISIS</topic><topic>HPLC</topic><topic>HYDROLYSE</topic><topic>LYCOPERSICON ESCULENTUM</topic><topic>SPECTROMETRIE DE MASSE</topic><topic>STRUCTURE CHIMIQUE</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Osman, Stanley F</creatorcontrib><creatorcontrib>Gerard, Herve C</creatorcontrib><creatorcontrib>Fett, William F</creatorcontrib><creatorcontrib>Moreau, Robert A</creatorcontrib><creatorcontrib>Dudley, Robert L</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of agricultural and food chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Osman, Stanley F</au><au>Gerard, Herve C</au><au>Fett, William F</au><au>Moreau, Robert A</au><au>Dudley, Robert L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Method for the Production and Characterization of Tomato Cutin Oligomers</atitle><jtitle>Journal of agricultural and food chemistry</jtitle><addtitle>J. Agric. Food Chem</addtitle><date>1995-08-01</date><risdate>1995</risdate><volume>43</volume><issue>8</issue><spage>2134</spage><epage>2137</epage><pages>2134-2137</pages><issn>0021-8561</issn><eissn>1520-5118</eissn><coden>JAFCAU</coden><abstract>A series of oligomeric fragments can be obtained by partial alkaline hydrolysis of cutin. The oligomers obtained from tomato cutin were analyzed by high-performance liquid chromatography-mass spectrometry and the major products were characterized as linear dimeric esters of omega,8-, omega,9-, and omega,10-dihydroxyhexadecanoic acids, the major monomers of tomato cutin. Analysis of the products obtained from tomato cutin by treatment with cutinase suggests an exo mode of depolymerization for this enzyme</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/jf00056a033</doi><tpages>4</tpages></addata></record> |
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subjects | ACTIVIDAD ENZIMATICA ACTIVITE ENZYMATIQUE Agronomy. Soil science and plant productions BEURRE VEGETAL Biological and medical sciences Chemical constitution Economic plant physiology ESPECTROMETRIA DE MASAS ESTER ESTERASAS ESTERASE ESTERES ESTRUCTURA QUIMICA Fundamental and applied biological sciences. Psychology GRASAS VEGETALES HIDROLISIS HPLC HYDROLYSE LYCOPERSICON ESCULENTUM SPECTROMETRIE DE MASSE STRUCTURE CHIMIQUE |
title | Method for the Production and Characterization of Tomato Cutin Oligomers |
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