Densities and Speeds of Sound of Jatropha curcas Biodiesel + (C4–C5) Alkan-1-ol Binary Mixtures

Densities (ρmix) and speeds of sound (u mix) for binary blends of Jatropha curcas biodiesel (1) + n-butanol or n-pentanol (2) were measured at T = (288.15 to 308.15) K and atmospheric pressure, over the entire composition range, with the help of a density and sound velocity meter (DSA 5000 M, Anton...

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Veröffentlicht in:Journal of chemical and engineering data 2012-08, Vol.57 (8), p.2236-2242
Hauptverfasser: Kumar, Satish, Sharma, Vinod Kumar, Lim, Wonsub, Cho, Jae Hyun, Moon, Il
Format: Artikel
Sprache:eng
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Zusammenfassung:Densities (ρmix) and speeds of sound (u mix) for binary blends of Jatropha curcas biodiesel (1) + n-butanol or n-pentanol (2) were measured at T = (288.15 to 308.15) K and atmospheric pressure, over the entire composition range, with the help of a density and sound velocity meter (DSA 5000 M, Anton Paar). The density values were used to evaluate the excess molar volumes V mix E. The Redlich–Kister polynomial equation was adopted to compute and correlate the results, and a good agreement has been observed between experimental and calculated values. It has been observed that the ρ and u values of pure components and their binary blends decreased with respect to temperature. Further, results have been analyzed in terms of molecular forces functioning between biodiesel and alcohols.
ISSN:0021-9568
1520-5134
DOI:10.1021/je300256m