Vapor Pressure of Solid Bis(2-chloroethyl) Sulfide

Vapor Pressure of Solid Bis(2-chloroethyl) Sulfide

The vapor pressure of the vesicant chemical warfare agent, bis(2-chloroethyl) sulfide (also known as sulfur mustard or HD), has been measured at T = (−25 to +20) °C using a modified ASTM vapor saturation methodology. This work represents the initial report of the measured vapor pressure of HD below...

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Veröffentlicht in:Journal of chemical and engineering data 2006-07, Vol.51 (4), p.1331-1334
Hauptverfasser: Buchanan, James H, Buettner, Leonard C, Tevault, David E
Format: Artikel
Sprache:eng
Schlagworte:
Chemical thermodynamics
Chemistry
Elements, mineral and organic compounds
Exact sciences and technology
General and physical chemistry
Thermodynamic properties
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Zusammenfassung:The vapor pressure of the vesicant chemical warfare agent, bis(2-chloroethyl) sulfide (also known as sulfur mustard or HD), has been measured at T = (−25 to +20) °C using a modified ASTM vapor saturation methodology. This work represents the initial report of the measured vapor pressure of HD below its melting point, +14.45 °C. The data measured for solid-phase HD are consistent with the previously reported enthalpy of fusion and liquid-phase vapor pressure of HD.
ISSN:0021-9568
1520-5134
DOI:10.1021/je060077o