Solubility of carbon monoxide in 1,4-dioxane
The solubility of CO in 1,4-dioxane was determined as a function of pressure (7-70 atm) and temperature (80-173/sup 0/C). An expression is given for solubility that relates the mole fraction and partial pressure of CO (in atmospheres) and the temperature in degrees Kelvin. The results, analyzed in t...
Gespeichert in:
| Veröffentlicht in: | J. Chem. Eng. Data; (United States) 1984-01, Vol.29 (1), p.36-39 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 39 |
|---|---|
| container_issue | 1 |
| container_start_page | 36 |
| container_title | J. Chem. Eng. Data; (United States) |
| container_volume | 29 |
| creator | Veleckis, Ewald Hacker, David S |
| description | The solubility of CO in 1,4-dioxane was determined as a function of pressure (7-70 atm) and temperature (80-173/sup 0/C). An expression is given for solubility that relates the mole fraction and partial pressure of CO (in atmospheres) and the temperature in degrees Kelvin. The results, analyzed in terms of the Krichevsky-Ilinskaya equation, showed that the partial molar volume of CO was independent of pressure and that the isobaric Henry's law was obeyed in the ranges studied. Comparisons with other solvents showed that, on the basis of CO dissolution characteristics, 1,4-dioxane can be classified better with polar than with nonpolar solvents. |
| doi_str_mv | 10.1021/je00035a013 |
| format | Article |
| fullrecord | <record><control><sourceid>istex_osti_</sourceid><recordid>TN_cdi_crossref_primary_10_1021_je00035a013</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_TPS_HWBFXSFM_C</sourcerecordid><originalsourceid>FETCH-LOGICAL-a364t-d2cbe64b3dd6b67e34aa2cd8045fe456effc662ad36edadeeac3a24d1b801f93</originalsourceid><addsrcrecordid>eNpt0M1KAzEUBeAgCtbqyhcY3Liw0fxPu9RirVBRaEF3IZPcYOo0kckU2rd3ZERcuLqL-3HgHITOKbmmhNGbNRBCuDSE8gM0oJIRLCkXh2hAujeeSDU-Ric5rzsmSkYHaLRM9bYKdWj3RfKFNU2VYrFJMe2CgyLEgo4EdiHtTIRTdORNneHs5w7Rana_ms7x4vnhcXq7wIYr0WLHbAVKVNw5VakSuDCGWTcmQnoQUoH3VilmHFfgjAMwlhsmHK3GhPoJH6KLPjblNuhsQwv23aYYwbZackaoEh266pFtUs4NeP3ZhI1p9poS_T2G_jNGp3GvQ25h90tN86FVyUupVy9LPX-9m70tZ0962vnL3hub9Tptm9j1_Tf5CzrtbMU</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Solubility of carbon monoxide in 1,4-dioxane</title><source>ACS Publications</source><creator>Veleckis, Ewald ; Hacker, David S</creator><creatorcontrib>Veleckis, Ewald ; Hacker, David S ; Argonne National Lab., IL</creatorcontrib><description>The solubility of CO in 1,4-dioxane was determined as a function of pressure (7-70 atm) and temperature (80-173/sup 0/C). An expression is given for solubility that relates the mole fraction and partial pressure of CO (in atmospheres) and the temperature in degrees Kelvin. The results, analyzed in terms of the Krichevsky-Ilinskaya equation, showed that the partial molar volume of CO was independent of pressure and that the isobaric Henry's law was obeyed in the ranges studied. Comparisons with other solvents showed that, on the basis of CO dissolution characteristics, 1,4-dioxane can be classified better with polar than with nonpolar solvents.</description><identifier>ISSN: 0021-9568</identifier><identifier>EISSN: 1520-5134</identifier><identifier>DOI: 10.1021/je00035a013</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>400201 - Chemical & Physicochemical Properties ; 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ; CARBON COMPOUNDS ; CARBON MONOXIDE ; CARBON OXIDES ; CHALCOGENIDES ; DATA ; DIOXANE ; EXPERIMENTAL DATA ; HETEROCYCLIC COMPOUNDS ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; NUMERICAL DATA ; ORGANIC COMPOUNDS ; ORGANIC OXYGEN COMPOUNDS ; OXIDES ; OXYGEN COMPOUNDS ; SOLUBILITY ; SOLVENT PROPERTIES</subject><ispartof>J. Chem. Eng. Data; (United States), 1984-01, Vol.29 (1), p.36-39</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a364t-d2cbe64b3dd6b67e34aa2cd8045fe456effc662ad36edadeeac3a24d1b801f93</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/je00035a013$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/je00035a013$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,885,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/5320164$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Veleckis, Ewald</creatorcontrib><creatorcontrib>Hacker, David S</creatorcontrib><creatorcontrib>Argonne National Lab., IL</creatorcontrib><title>Solubility of carbon monoxide in 1,4-dioxane</title><title>J. Chem. Eng. Data; (United States)</title><addtitle>J. Chem. Eng. Data</addtitle><description>The solubility of CO in 1,4-dioxane was determined as a function of pressure (7-70 atm) and temperature (80-173/sup 0/C). An expression is given for solubility that relates the mole fraction and partial pressure of CO (in atmospheres) and the temperature in degrees Kelvin. The results, analyzed in terms of the Krichevsky-Ilinskaya equation, showed that the partial molar volume of CO was independent of pressure and that the isobaric Henry's law was obeyed in the ranges studied. Comparisons with other solvents showed that, on the basis of CO dissolution characteristics, 1,4-dioxane can be classified better with polar than with nonpolar solvents.</description><subject>400201 - Chemical & Physicochemical Properties</subject><subject>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)</subject><subject>CARBON COMPOUNDS</subject><subject>CARBON MONOXIDE</subject><subject>CARBON OXIDES</subject><subject>CHALCOGENIDES</subject><subject>DATA</subject><subject>DIOXANE</subject><subject>EXPERIMENTAL DATA</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>NUMERICAL DATA</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC OXYGEN COMPOUNDS</subject><subject>OXIDES</subject><subject>OXYGEN COMPOUNDS</subject><subject>SOLUBILITY</subject><subject>SOLVENT PROPERTIES</subject><issn>0021-9568</issn><issn>1520-5134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1984</creationdate><recordtype>article</recordtype><recordid>eNpt0M1KAzEUBeAgCtbqyhcY3Liw0fxPu9RirVBRaEF3IZPcYOo0kckU2rd3ZERcuLqL-3HgHITOKbmmhNGbNRBCuDSE8gM0oJIRLCkXh2hAujeeSDU-Ric5rzsmSkYHaLRM9bYKdWj3RfKFNU2VYrFJMe2CgyLEgo4EdiHtTIRTdORNneHs5w7Rana_ms7x4vnhcXq7wIYr0WLHbAVKVNw5VakSuDCGWTcmQnoQUoH3VilmHFfgjAMwlhsmHK3GhPoJH6KLPjblNuhsQwv23aYYwbZackaoEh266pFtUs4NeP3ZhI1p9poS_T2G_jNGp3GvQ25h90tN86FVyUupVy9LPX-9m70tZ0962vnL3hub9Tptm9j1_Tf5CzrtbMU</recordid><startdate>19840101</startdate><enddate>19840101</enddate><creator>Veleckis, Ewald</creator><creator>Hacker, David S</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19840101</creationdate><title>Solubility of carbon monoxide in 1,4-dioxane</title><author>Veleckis, Ewald ; Hacker, David S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a364t-d2cbe64b3dd6b67e34aa2cd8045fe456effc662ad36edadeeac3a24d1b801f93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1984</creationdate><topic>400201 - Chemical & Physicochemical Properties</topic><topic>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)</topic><topic>CARBON COMPOUNDS</topic><topic>CARBON MONOXIDE</topic><topic>CARBON OXIDES</topic><topic>CHALCOGENIDES</topic><topic>DATA</topic><topic>DIOXANE</topic><topic>EXPERIMENTAL DATA</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>NUMERICAL DATA</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC OXYGEN COMPOUNDS</topic><topic>OXIDES</topic><topic>OXYGEN COMPOUNDS</topic><topic>SOLUBILITY</topic><topic>SOLVENT PROPERTIES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Veleckis, Ewald</creatorcontrib><creatorcontrib>Hacker, David S</creatorcontrib><creatorcontrib>Argonne National Lab., IL</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Chem. Eng. Data; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Veleckis, Ewald</au><au>Hacker, David S</au><aucorp>Argonne National Lab., IL</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solubility of carbon monoxide in 1,4-dioxane</atitle><jtitle>J. Chem. Eng. Data; (United States)</jtitle><addtitle>J. Chem. Eng. Data</addtitle><date>1984-01-01</date><risdate>1984</risdate><volume>29</volume><issue>1</issue><spage>36</spage><epage>39</epage><pages>36-39</pages><issn>0021-9568</issn><eissn>1520-5134</eissn><abstract>The solubility of CO in 1,4-dioxane was determined as a function of pressure (7-70 atm) and temperature (80-173/sup 0/C). An expression is given for solubility that relates the mole fraction and partial pressure of CO (in atmospheres) and the temperature in degrees Kelvin. The results, analyzed in terms of the Krichevsky-Ilinskaya equation, showed that the partial molar volume of CO was independent of pressure and that the isobaric Henry's law was obeyed in the ranges studied. Comparisons with other solvents showed that, on the basis of CO dissolution characteristics, 1,4-dioxane can be classified better with polar than with nonpolar solvents.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/je00035a013</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-9568 |
| ispartof | J. Chem. Eng. Data; (United States), 1984-01, Vol.29 (1), p.36-39 |
| issn | 0021-9568 1520-5134 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_je00035a013 |
| source | ACS Publications |
| subjects | 400201 - Chemical & Physicochemical Properties 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) CARBON COMPOUNDS CARBON MONOXIDE CARBON OXIDES CHALCOGENIDES DATA DIOXANE EXPERIMENTAL DATA HETEROCYCLIC COMPOUNDS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC OXYGEN COMPOUNDS OXIDES OXYGEN COMPOUNDS SOLUBILITY SOLVENT PROPERTIES |
| title | Solubility of carbon monoxide in 1,4-dioxane |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T16%3A43%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Solubility%20of%20carbon%20monoxide%20in%201,4-dioxane&rft.jtitle=J.%20Chem.%20Eng.%20Data;%20(United%20States)&rft.au=Veleckis,%20Ewald&rft.aucorp=Argonne%20National%20Lab.,%20IL&rft.date=1984-01-01&rft.volume=29&rft.issue=1&rft.spage=36&rft.epage=39&rft.pages=36-39&rft.issn=0021-9568&rft.eissn=1520-5134&rft_id=info:doi/10.1021/je00035a013&rft_dat=%3Cistex_osti_%3Eark_67375_TPS_HWBFXSFM_C%3C/istex_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |