Solubility of carbon monoxide in 1,4-dioxane

The solubility of CO in 1,4-dioxane was determined as a function of pressure (7-70 atm) and temperature (80-173/sup 0/C). An expression is given for solubility that relates the mole fraction and partial pressure of CO (in atmospheres) and the temperature in degrees Kelvin. The results, analyzed in t...

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Veröffentlicht in:	J. Chem. Eng. Data; (United States) 1984-01, Vol.29 (1), p.36-39
Hauptverfasser:	Veleckis, Ewald, Hacker, David S
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) CARBON COMPOUNDS CARBON MONOXIDE CARBON OXIDES CHALCOGENIDES DATA DIOXANE EXPERIMENTAL DATA HETEROCYCLIC COMPOUNDS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC OXYGEN COMPOUNDS OXIDES OXYGEN COMPOUNDS SOLUBILITY SOLVENT PROPERTIES
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Zusammenfassung:	The solubility of CO in 1,4-dioxane was determined as a function of pressure (7-70 atm) and temperature (80-173/sup 0/C). An expression is given for solubility that relates the mole fraction and partial pressure of CO (in atmospheres) and the temperature in degrees Kelvin. The results, analyzed in terms of the Krichevsky-Ilinskaya equation, showed that the partial molar volume of CO was independent of pressure and that the isobaric Henry's law was obeyed in the ranges studied. Comparisons with other solvents showed that, on the basis of CO dissolution characteristics, 1,4-dioxane can be classified better with polar than with nonpolar solvents.
ISSN:	0021-9568 1520-5134
DOI:	10.1021/je00035a013