Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO 2 and Water

Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO 2 and Water

A catalytic protocol that reliably predicts and controls the site-selective incorporation of CO to a wide range of unsaturated hydrocarbons utilizing water as formal hydride source is described. This platform unlocks an opportunity to catalytically repurpose three abundant, orthogonal feedstocks und...

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Veröffentlicht in:Journal of the American Chemical Society 2017-09, Vol.139 (35), p.12161-12164
Hauptverfasser: Gaydou, Morgane, Moragas, Toni, Juliá-Hernández, Francisco, Martin, Ruben
Format: Artikel
Sprache:eng
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Beschreibung
Zusammenfassung:A catalytic protocol that reliably predicts and controls the site-selective incorporation of CO to a wide range of unsaturated hydrocarbons utilizing water as formal hydride source is described. This platform unlocks an opportunity to catalytically repurpose three abundant, orthogonal feedstocks under mild conditions.
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.7b07637