Templated Synthesis of Uniform Perovskite Nanowire Arrays

While the chemical composition of semiconducting metal halide perovskites can be precisely controlled in thin films for photovoltaic devices, the synthesis of perovskite nanostructures with tunable dimensions and composition has not been realized. Here, we describe the templated synthesis of uniform...

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Veröffentlicht in:Journal of the American Chemical Society 2016-08, Vol.138 (32), p.10096-10099
Hauptverfasser: Ashley, Michael J, O’Brien, Matthew N, Hedderick, Konrad R, Mason, Jarad A, Ross, Michael B, Mirkin, Chad A
Format: Artikel
Sprache:eng
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Zusammenfassung:While the chemical composition of semiconducting metal halide perovskites can be precisely controlled in thin films for photovoltaic devices, the synthesis of perovskite nanostructures with tunable dimensions and composition has not been realized. Here, we describe the templated synthesis of uniform perovskite nanowires with controlled diameter (50–200 nm). Importantly, by providing three examples (CH3NH3PbI3, CH3NH3PbBr3, and Cs2SnI6), we show that this process is composition general and results in oriented nanowire arrays on transparent conductive substrates.
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.6b05901