Polythiophene Hybrids of Transition-Metal Bis(salicylidenimine)s:  Correlation between Structure and Electronic Properties

Polythiophene Hybrids of Transition-Metal Bis(salicylidenimine)s:  Correlation between Structure and Electronic Properties

The synthesis, electrochemistry, and spectroscopic behavior of tetradentate bis(salicylidenimine) transition metal complexes 5 − 9 are reported. Appending these complexes with 3,4-ethylenedioxythiophene (EDOT) moieties allows for electrochemical polymerization at much lower potentials than the paren...

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Veröffentlicht in:Journal of the American Chemical Society 1999-09, Vol.121 (38), p.8825-8834
Hauptverfasser: Kingsborough, Richard P, Swager, Timothy M
Format: Artikel
Sprache:eng
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Zusammenfassung:The synthesis, electrochemistry, and spectroscopic behavior of tetradentate bis(salicylidenimine) transition metal complexes 5 − 9 are reported. Appending these complexes with 3,4-ethylenedioxythiophene (EDOT) moieties allows for electrochemical polymerization at much lower potentials than the parent salen complexes. The resulting polymers display well-defined organic-based electrochemistry at potentials
ISSN:0002-7863
1520-5126
DOI:10.1021/ja991285m