Induction of Liquid Crystallinity by Host−Guest Interactions
A molecular clip is described which binds aromatic guests by an induced fit mechanism. It contains twelve long aliphatic chains and can evoke liquid-crystalline properties in a variety of molecules, including polymers and porphyrins, by a process of molecular recognition.
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| Veröffentlicht in: | Journal of the American Chemical Society 1997-01, Vol.119 (2), p.283-291 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A molecular clip is described which binds aromatic guests by an induced fit mechanism. It contains twelve long aliphatic chains and can evoke liquid-crystalline properties in a variety of molecules, including polymers and porphyrins, by a process of molecular recognition. |
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| ISSN: | 0002-7863 1520-5126 |
| DOI: | 10.1021/ja9603113 |