Pd(OAc)2 Catalyzed Olefination of Highly Electron-Deficient Perfluoroarenes

Pd(OAc)2 Catalyzed Olefination of Highly Electron-Deficient Perfluoroarenes

An efficient, Pd(OAc)2 catalyzed method for direct olefination of highly electron-deficient perfluoroarenes was developed. The reaction scope includes a series of activated and nonactivated alkenes in moderate to high yields with moderate to high regio- and stereoselectivities.

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Veröffentlicht in:Journal of the American Chemical Society 2010-04, Vol.132 (13), p.4506-4507
Hauptverfasser: Zhang, Xingang, Fan, Shilu, He, Chun-Yang, Wan, Xiaolong, Min, Qiao-Qiao, Yang, Jie, Jiang, Zhong-Xing
Format: Artikel
Sprache:eng
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Zusammenfassung:An efficient, Pd(OAc)2 catalyzed method for direct olefination of highly electron-deficient perfluoroarenes was developed. The reaction scope includes a series of activated and nonactivated alkenes in moderate to high yields with moderate to high regio- and stereoselectivities.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja908434e